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“双碳”目标下土壤溶解性有机碳环境行为与协同管控路径研究进展

Research Progress in Environmental Behaviors and Collaborative Control Pathways of Soil Dissolved Organic Carbon under “Dual Carbon” Goals

  • 摘要: 土壤溶解性有机碳(DOC)是土壤有机碳库中活性最高、迁移性最强、环境响应最敏感的组分,在陆地生态系统碳循环、土壤固碳增汇及污染物迁移转化过程中发挥关键枢纽作用。现有研究多考察DOC在碳循环调控或污染物迁移中的单一功能,鲜有关注两者的协同效应与权衡机制,难以支撑“双碳”目标下土壤碳汇提升与污染风险协同管控的现实需求。本文系统梳理了国内外土壤DOC的研究进展,构建“动态变化—迁移转化—环境效应”耦合分析框架,阐明了DOC含量与组成的时空变异特征、多因子驱动机制及多途径迁移转化规律,揭示了DOC对土壤碳库源—汇转换的调控机制,明确了其作为重金属与有机污染物迁移载体的环境行为与生态风险,重点剖析了固碳增汇与污染阻控的协同权衡关系及管控路径,同时指出现有研究在来源解析、方法标准统一、微观界面机制、多过程耦合模拟等方面依然面临诸多核心挑战。未来研究需融合高分辨质谱、同位素示踪与同步辐射光谱等先进技术,深化矿物—DOC—微生物界面反应机制研究,量化固碳增汇与污染阻控的协同阈值,构建以碳汇提升和污染风险削减为双目标的靶向调控技术体系,推动DOC由污染物载体向固碳引擎的功能转化,为土壤健康管理、流域生态安全及国家“双碳”战略实施提供理论依据与技术支撑。

     

    Abstract: Soil dissolved organic carbon(DOC) is the most active, mobile, and environmentally responsive component of the soil organic carbon pool, playing a pivotal role in terrestrial ecosystem carbon cycling, soil carbon sequestration and sink enhancement, as well as the transport and transformation of pollutants. Current research often isolates the role of DOC in either regulating carbon cycling or facilitating pollutant transport, with few studies addressing the synergistic effects and trade-off mechanisms between the two. This makes it difficult to meet the practical demands of coordinating soil carbon sink enhancement with pollution risk control under “dual carbon” goals. This paper systematically reviews recent advances in soil DOC research worldwide and develops an integrated framework linking “dynamics-transport/transformation-environmental effects”. It elucidates the spatiotemporal variation in DOC concentration and composition, the multi-factor driving mechanisms, and pathways of DOC transport and transformation. Furthermore, it reveals how DOC regulates the source-sink balance of soil carbon pools and clarifies its environmental behavior and ecological risks as a carrier of heavy metals and organic pollutants. In particular, it analyzes the synergistic mechanisms and trade-offs between carbon sequestration enhancement and pollution control, and proposes integrated regulation pathways. Key challenges are identified, including source apportionment, standardization of analytical methods, micro-scale interfacial mechanisms, and coupled multi-process simulation. Future research should integrate advanced techniques such as high-resolution mass spectrometry, isotope tracing, and synchrotron radiation spectroscopy to deepen mechanistic understanding of mineral-DOC-microbe interfacial reactions. It will be critical to quantify the synergistic thresholds between carbon sequestration enhancement and pollution control, develop targeted regulation technologies that simultaneously enhance carbon sinks and reduce pollution risks, and promote the functional transformation of DOC from a pollutant carrier to a carbon sequestration engine. These efforts will provide theoretical foundations and technical support for soil health management, watershed ecological security, and the implementation of China's carbon peaking and carbon neutrality strategies.