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浙江典型农田土壤有效镉含量特征及其影响因子分析

Content of Available Cd in Typical Farmland of Zhejiang Province and Its Influencing Factors

  • 摘要: 采用相关性分析、多元回归、随机森林及结构方程模型等方法,在R平台分析了3564个土壤样品,探究了浙江省农田土壤有效镉(A.Cd)含量特征及其土壤影响因子。结果表明:A.Cd含量为0.001~189.000mg/kg,变异系数为595%;94.8%的样品低于农用地风险筛选值0.4 mg/kg(水田pH值介于5.0~6.5)。在全样本及“母质—亚类—土属—利用方式”各分类单元中,有机质(OM)、pH值、有效硼(A.B)、有效铜(A.Cu)、有效钼(A.Mo)、有效锰(A.Mn)、有效铁(A.Fe)与有效锌(A.Zn)含量是土壤A.Cd含量的共同驱动因子,按重要性由大到小依次为A.B > A.Cu > A.Mo > A.Mn > A.Zn > A.Fe,直接或通过中介因子OM含量、pH值等间接影响A.Cd含量,其关系可用多元线性回归方程描述。在全样本、新浅海沉积物母质发育土壤中,A.Cu对A.Cd变异的贡献最大;在渗育水稻土亚类、淡涂田土属和水稻油菜轮作田中以A.B为主导因子;在脱潜水稻土亚类和洪积泥砂田土属中以A.Mn的重要性最大;单季晚稻田中A.Mo的解释率最高。

     

    Abstract: For exploration of the content of available Cd(A.Cd)and its influencing factors in typical farmland of Zhejiang Province, the methods including correlation analysis, multiple linear regression, random forests model, and structural equation model were applied to analyze the data on a total 3564 soil samples on the R platform. The results show that the A.Cd content ranges from 0.001 to 189.000 mg/kg, with a coefficient of variation of 595%, and is lower than the screening value of 0.4 mg/kg for soil pollution risk in agricultural land in 94.8% of the soil samples(pH value 5.0~6.5 of the paddy field). Under scenarios as distinct parent soil, subtype, soil genus, and soil use pattern, the shared soil factors affecting soil A.Cd content are organic matter(OM), pH, available B(A.B), available Cu(A.Cu), available Mo(A.Mo), available Mn(A.Mn), available Fe(A.Fe), and available Zn(A.Zn), with rank by importance as A.B>A.Cu>A.Mo>A.Mn>A.Zn>A.Fe. Their relationships with A.Cd are directly or indirectly influenced or regulated by OM, pH, whose relatives could be quantitatively described using a linear regression equation. In the above-mentioned scenarios, the influence of these soil factors on A.Cd content varies, such as A.Cu with the greatest influence in the full sample scenario, the soil developed from neo-neritic sediments of the parent soil, and the soil developed from take-off the latent paddy soil of sub-class, A.B with the greatest influence in the percogenic paddy soils of sub-class, thin-layer mud fields of soil genus, and the rice-rapeseed rotation field of soil use pattern, A.Mn with the greatest influence in the proluvial silt soil of soil genus, and A.Mo with the greatest influence in the soil with single cropping later rice of soil use pattern.